Unlock Roger Jr.:
Defeat the game with Kazuya
Unlock Anna Williams:
Defeat the game in Story Mode 2 times
Unlock Baek:
Defeat the game in Story mode 3 times

Unlock Bruce Irvin:
Defeat the game in Story Mode 4 times

Unlock Wang:
Defeat Time Attack, Story or Battle mode 4 times

Unlock Kuma:
Defeat Time Attack, Story or Battle mode 5 times
Unlock Ganryu:
Defeat Time Attack, Story or Battle mode 6 times

Unlock Mokujin:
Defeat Time Attack, Story or Battle mode 7 times

Unlock Heihachi:
Defeat Time Attack, Story or Battle mode 8 times
Unlock School Girl Ling:
Obtain 50 wins in vs mode, then press R1 to select the character. Note: R1 must be set to RP + LP.
Unlock Eddy Gordo:
Eddy is an extra outfit you buy for Christie
(500,000G on console instead of the 400,000G price tag on the arcade version).

Unlock Devil Jin:
Complete Tekken: Devil Within mini-game to play as Devil Jin