| Unlockable: | How to unlock: |
| Zhuge Liang | Clear Musou Mode with 1 Shu character |
| Liu Bei | Clear Musou Mode with 3 Shu characters |
| Zhang Liao | Clear Musou Mode with 1 Wei character |
| Cao Cao | Clear Musou Mode with 3 Wei characters |
| Gan Ning | Clear Musou Mode with 1 Wu character |
| Sun Jian | Clear Musou Mode with 3 Wu characters |
| Diao Chan | Clear Musou Mode with 1 character from each Kingdom |
| Lu Bu | Clear Musou Mode with Liu Bei, Cao Cao, and Sun Jian |
| Dong Zhuo | Clear Musou Mode with Lu Bu |
| Ma Chao | Succeed in 2 battle objectives on the Wei side of Han Zhong Attack Defense Battle |
| Huang Zhong | Succeed in 1 battle objective on the Wei side of Ding Jun Mountain |
| Wei Yan | Succeed in 2 battle objectives on the Shu side of WuZhang Plains and finish battle with Wei Yan alive |
| Guan Ping | Succeed in 2 battle objectives on the Shu side of Fan Castle and finish battle with Guan Ping alive |
| Pang Tong | Succeed in 3 battle objectives at Cheng Du battle and finish battle with Pang Tong alive |
| Xiahou Yuan | Succeed in 1 battle objective on the Shu side of Ding Jun Mountain |
| Xu Huang | Succeed in 2 battle objectives on the Wei/Wu side of Fan Castle |
