| Unlockable: | How to unlock: |
| 00 Agent (30) | Public Match: Reach level 50 (00 Agent Grade 0). |
| 007 (50) | Complete all levels on a 'Classic' difficulty. |
| A Farewell to Arms (50) | Multiplayer: Enter 00 Specialization. |
| Above and Beyond a 00 (30) | Complete three of the '007' level trials. |
| All That Glitters (10) | Earn a 3 star rating in any mission of the Challenges mode. |
| All the Time in the World (40) | Public Match: Play for more than 24 hours. |
| Around the world one more time (20) | Get 100% collection rating for 'Moonraker'. |
| Boys with Toys (10) | Campaign: Buy all of the attachments for one weapon class. |
| Challenger (20) | Earn a 1 star rating in each mission of the Challenges mode. |
| Clandestine (10) | Campaign: Collect 100% of all organization intel. |
| Counter-Sniper (25) | Public Match: Kill 50 players while they are aiming down the scope of a sniper rifle. |
| Danger! High Voltage (10) | Public Match: Get 25 electrocution kills as Zao or Gustav Graves. |
| Die Another Day (15) | Complete the 'Die Another Day' mission. |
| Disarmed and Dangerous (20) | Public Match: In Escalation demote an enemy who is armed with the RPG. |
| Distracting (10) | Distract an enemy. |
| Everything or Nothing (5) | Complete all of the trials on any one level. |
| Extended Operative (20) | Complete eight of the 'Operative' level trials. |
| Fascination with all things gold (60) | Get 100% of all available stars in the Challenges mode. |
| Goldfinger (15) | Complete the 'Goldfinger' mission. |
| Happy Snapper (10) | Campaign: Take a photograph of the crocodile. |
| Hold the Line (30) | Public Match: Win a Data Miner match without being killed. |
| I expect you to die (20) | Get 100% collection rating for 'Goldfinger'. |
| Laser Eraser (15) | Public Match: Win a match using only laser-based weapons. |
| Licence To Kill (15) | Complete the 'License To Kill' mission. |
| Making it Personal (10) | Campaign: Collect 100% of all character bio intel. |
| Master at Arms (20) | Make an elimination with every weapon class. |
| Midas Touch (15) | Public Match: Win a match on Main Vault, Smelting Room and Loading Bay. |
| Moonraker (15) | Complete the 'Moonraker' mission. |
| More Than an Agent (25) | Complete six of the 'Agent' level trials. |
| Never happened to the other guy (20) | Get 100% collection rating for 'O.H.M.S.S.' |
| O.H.M.S.S. (15) | Complete the 'O.H.M.S.S.' mission. |
| Omega Virus (15) | Public Match: Kill an enemy who has completed the campaign or who already has this Achievement. |
| One small step for a man (0) | Experience zero-g. |
| People Power (10) | Campaign: Collect 30% of all character bio intel. |
| Positively shocking! (12) | Take out two enemies with one shock dart. |
| Return to Sender (35) | Public Match: In Bomb Defuse disarm the bomb and plant it at enemy base without getting killed. |
| Scream if you want to go faster (10) | Campaign: Give someone an exciting training experience. |
| Secret Agent (50) | Complete all levels on 'Agent' difficulty or higher. |
| Shaken, but not Stirred (10) | Public Match: Survive 50 explosions while using Reactive Armor. |
| Shooting Star (20) | Get 30% of all available stars in the Challenges mode. |
| Signature (7) | Campaign: Reach level three weapon proficiency with the P99. |
| Spend the money quickly Mr. Bond (20) | Campaign: Be awarded a total of 10,000 XP. |
| Standards of Physical Perfection (30) | Campaign: Acquire all of the MI6 training modules. |
| Star Struck (40) | Get 60% of all available stars in the Challenges mode. |
| Unlocked and Loaded (5) | Public Match: Reach level 6 (Midshipman). |
| Very novel Q (10) | Campaign: Upgrade a gadget to its highest level. |
| Vodka martini, plenty of ice... (20) | Get 100% collection rating for 'Die Another Day'. |
| Web of Intrigue (10) | Campaign: Collect 30% of all organization intel. |
| With or Without Q (16) | Reach Grave's plane without using any in-car gadgets. |
| You prepare for the unexpected (20) | Get 100% collection rating for 'License To Kill'. |
.